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We don't have any details as to the daily activities of your wife and children, but unless there is some pressing reason to be concerned for their safety, I would advise that you seriously consider the risks vs. the benefits of having her armed at this time.

Perhaps less lethal instruments (OC spray) might be the safer thing until the children are older?

Clearly, purse carry would present an opportunity for inquisitive minds/hands to get into potentially lethal trouble. Even if She kept the weapon on her person, you would have to extremely careful not to allow access to it, 100 % of the time. Then there is the matter of safe storage in the interim. Just sounds too high risk to me...at this time.