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I have been shooting since I was 4, I'm 56 now and I can never remember not owning a gun!
Here my 2 cents, first is your wife closing her eyes when she shoots? Does she yank the trigger rather than squeeze it?
The best way to find out is to load the gun for her, do not put a round in the chamber, do this so she believes she has a live round! If she yanks the trigger it will be very apparent!
What kind of hearing protection are you using? If it's ear plugs get her some ear muffs and make sure she has eye protection also!
Basically she's afraid of shooting and this has created her bad habits and her bad habit is preventing her from concentrating on hitting her target!