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The hazmat fee covers the cost of extra training for the transportation company employees, ALL the paperwork and documentation, and the extra insurance they have to carry when they transport explosives. Plus, there are certain classes of goods that can't be transported on trucks containing explosives. All that costs bucks.

Set a case of primers and a case of loaded ammo on the ground, and run a forklift tine into each case. See which one makes a big boom.